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Advanced organic chemistry, Class 11
·
Module 10
Advanced Addition and Oxidation/Reduction
1
Oxymercuration-Demercuration: Mechanism and Stereochemistry
Explain the mechanism, regiochemistry, and stereochemistry of oxymercuration-demercuration.
2
Hydroboration-Oxidation: Mechanism and Stereochemistry
Explain the mechanism, regiochemistry (anti-Markovnikov), and stereochemistry (syn-addition) of hydroboration-oxidation.
3
Alkene Hydration: Regioselectivity and Stereospecificity
Compare the regioselectivity and stereospecificity of the three major alkene hydration methods.
4
Ozonolysis of Alkenes and Alkynes
Describe the mechanism of ozonolysis for alkenes and alkynes and predict the products.
5
Epoxidation of Alkenes with Peroxy Acids
Describe the mechanism for epoxidation of alkenes with peroxy acids.
6
Syn-Dihydroxylation of Alkenes: KMnO4 & OsO4
Describe the mechanism for syn-dihydroxylation of alkenes using KMnO4 or OsO4.
Previous module
Addition to Alkenes and Alkynes
Next module
Advanced Nomenclature and Spectroscopic Evidence