Thermodynamics of Electrochemical Systems

Explain the relationship between Gibbs free energy change and cell potential for an electrochemical reaction.

Distinguish between galvanic and electrolytic cells in terms of energy conversion and spontaneity.

Calculate standard electrode potentials using tabulated reduction potentials.

Apply the Nernst equation to determine cell potential under non-standard conditions.

Calculate the thermodynamic minimum voltage required for water electrolysis under standard and non-standard conditions.

Interpret Pourbaix diagrams to predict the thermodynamic stability of species in aqueous solutions.