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Advanced organic chemistry, Class 11
·
Module 1
Quantum Foundations of Chemical Bonding
1
Orbital Shapes from Schrödinger's Equation
Explain the shapes of s, p, and d orbitals from solutions to the Schrödinger equation.
2
Hund's Rule and Pauli Principle: Exchange Energy and Spin Statistics
Explain the origin of Hund's rule and the Pauli exclusion principle in terms of electron exchange energy and spin statistics.
3
Constructing Molecular Orbitals for Diatomic Molecules
Apply molecular orbital theory to construct bonding and antibonding orbitals for diatomic molecules.
4
Constructing Molecular Orbital Diagrams for Simple Sigma and Pi Systems
Construct molecular orbital energy diagrams for simple sigma and pi systems (e.g., ethene, ethyne).
5
Hybridization: Mixing Atomic Orbitals
Analyze hybridization as the mathematical mixing of atomic orbitals to form sp, sp2, and sp3 hybrids.
VSEPR and Hybridization: Predicting Molecular Geometry
Predict molecular geometry (e.g., linear, trigonal planar, tetrahedral) based on VSEPR theory and hybridization.
7
Orbital Overlap and Bond Strength
Relate orbital overlap to bond strength and explain why pi bonds are generally weaker than sigma bonds.
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Electronic Effects and Aromaticity