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Foundations of Statistical Mechanics
·
Module 1
Information, Probability, and Asymptotic Methods
1
Shannon Entropy & Maximum Entropy Principle
Define Shannon entropy and derive the principle of maximum entropy (MaxEnt) for constructing equilibrium probability distributions.
2
MaxEnt and the Exponential Family
Derive the general form of the exponential family of distributions (e.g., Gibbs distribution) from the MaxEnt principle subject to macroscopic constraints.
3
Moments and Cumulants via Generating Functions
Compute moments and cumulants of distributions using moment-generating and characteristic functions.
4
Central Limit Theorem for Sums of Independent Random Variables
Derive and apply the central limit theorem to sums of independent random variables.
5
Saddle-Point Approximation for Integrals
Evaluate integrals asymptotically using the saddle-point (steepest descent) approximation.
6
Large Deviation Principle and Cramér's Theorem
Define the large deviation principle and the rate function, stating Cramér's theorem for sums of IID random variables.
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Kinetic Theory and the Approach to Equilibrium